Ouma Shu from Guilty Crown I don't have a picture of him being serious but After one of his Friends died which I think was hase he became ruthless to everyone but for the sole reason of trying to make sure everyone survive
After temporarily becoming the Supreme King in season 3 of Yugioh Gx . Jaden in season 4 has Lost the carefree personality he had before the incident and became a much Mehr serious person . This is due to the fact that as the Supreme King Jaden hurt some of his closest friend and killed a lot of people .