Episode 1.01 - Pilot
"If It's Lovin' That Du Want (Part 2)" Von Rihanna Feat. Corey Gunz
Dinner Party, before Blair takes Nate into her room
"What Goes Around...Comes Around" Von Justin Timberlake
Dinner Party, after Serena leaves
"Hard to Live in the City" Von Albert Hammond Jr.
Limo ride to the "kiss of the lips" party
"The Gift" Von Engel & Airwaves
Blair and Chuck watch Serena leave with Dan
Episode 1.02 - The Wild Brunch
"Tell Me 'Bout It" Von Joss Stone
Blair, Chuck and the group having Brunch
"The Queen And I" Von Gym Class Heroes
Chuck gives Blair the key to his suite
"Shut Up And Drive" Von Rihanna
Blair reveals Serena's secret infront of Dan and the group
Episode 1.03 - Poison Ivy
"Glamorous" Von The Constance Billard Choir
Everyone walking into school
Episode 1.06 - The Handmaiden's Tale
"Take it to the top" Von 5 Alarm
Blair and Chuck at the ball
Episode 1.07 - Victor, Victrola
"So They Say" Von Classic
Chuck asks Blair about his idea
"Stripper" Von Soho Dolls
Chuck watching Blair at Victrola
"With Me" Von Sum 41
Blair and Chuck in the limo!
Episode 1.08 - Seventeen Candles
"One Week Of Danger" Von The Virgins
Blair flashback to the Limo.
Blair tells Chuck to leave her alone.
Serena sees Blair and Chuck kissing
"Love Is Colder Than Death" Von The Virgins
Chuck arrives at Blair's party
"How Does It Feel?" Von Eskimo Joe
Blair runs off from her birthday cake
"Radio Christiane" Von The Virgins
Chuck brings Blair her gift
Episode 1.10 - Hi, Society
"You're a Wolf" Von Sea Wolf
Blair and Chuck making out
"Secret" Von The Pierces
Everyone dancing at the ball
"Three Wishes" Von The Pierces
Chuck and Blair dance at the ball
Episode 1.12 - School Lies
"Ooh Yeah" Von Moby
Blair and Chuck Von the pool
"Come Flash All Du Ladies" Von The Filthy Youth
Blair takes the key from Chuck
"Orange" Von The Filthy Youth
Chuck confronts Blair
Episode 1.13 - A Thin Line Between Chuck and Nate
"You'll Change" Von Machine Translations
Chuck watches Nate and Blair together
"The Air We Breathe" Von The Figurines
Blair thinks back to the limo
Episode 1.17 - Woman on the Verge
"Fight Song" Von The Republic Tigers
Serena, Blair & Chuck arrive at the rehearsal dinner
"Everytime" Von lincoln Hawk
Nate, Blair & Chuck arrive at the concert
Episode 1.18 - Much 'I Do' About Nothing
"The Ice Is Getting Thinner" Von Death Cab For Cutie
Chuck's speech and Blair/Chuck dancing
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