The Doctor and River Song If Du didn't start shipping them from the very start (Silence in the Library/Forest of the Dead) which episode won Du over? Which scene (tell in comments)?
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The Time of Engel
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Flesh and Stone
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The Pandorica Opens
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The Big Bang
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The Impossible Astronaut
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Tag of the Moon
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A Good Man Goes to War
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Let's Kill Hitler
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Closing Time (River has one scene)
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The Wedding of River Song
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First Night ('Night and the Doctor' minisode)
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Last Night ('Night and the Doctor' minisode)
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I DID Liebe them from the very start!
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